Thermal decomposition and reaction sintering for synthesis of mullite-zirconia composite using kaolin, γ-alumina and zirconia

نویسندگان

چکیده

The refractory materials used in the wall of furnaces for glass melting can be prepared from mullite-zirconia composite material. mullite/zirconia was synthesized Iraqi kaolin, γ-alumina, and zirconia using thermal decomposition with reaction sintering at 1600 °C. Several batches were various ratios zirconia, compositions selected Al2O3-SiO2-ZrO2 phase diagram. different steps beginning milling starting materials, semi-dry uniaxial pressing, then reactive temperatures (1200, 1400, °C). predicted phases ZrO2 Al6Si2O13 identified by X-ray diffraction patterns according to diagram all batches. lower amount added mullite reduced porosity improved bulk density composite. expansion coefficient slightly increased addition zirconia. It also enhanced shock resistance Finally, mechanical properties increasing particles a matrix due transformation tetragonal monoclinic phase.

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ژورنال

عنوان ژورنال: Cerâmica

سال: 2021

ISSN: ['1678-4553', '0366-6913']

DOI: https://doi.org/10.1590/0366-69132021673812991